Diablo 2 LOD Utilities Page

Power Leveling Guide
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The how to on leveling 1-99 as fast as possible.

Level Range
Area (Difficulty)
Level 1 - 15
Tristram Runs (Normal)
Level 15 - 20
Tal Rasha's Tomb Runs (Normal)
Level 20 - 24
Secret Cow Level Runs (Normal)
Level 24
Ancients Quest (Normal)
Level 25 - 45
Baal Runs (Normal)
Level 45
Ancients Quest (Nightmare)*
Level 46 - 70
Baal Runs (Nightmare)
Level 70
Ancients Quest (Hell)*
Level 71-99
Baal Runs (Hell)

* If you are attempting to power level a character, you should probably get rushed through nightmare and hell, which is why you go right from Baal to the Ancients at the next difficulty.